I suppose yes if the PCDs are the same...the wheel would fit on however whether the rim will clear the brakes, I don't know.
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The E36 takes 5 bolts. Since you said the MR2 has 5 studs, check if the 5-position matches the E36.Wheels are probably the most common custom part that people will put on their BMW.Wheels are expensive, at least they should be, so if you are looking at a new set of wheels at an unbelievable price.Some mercs are the same as some Falcons but thats it.
Narrowing down the size, type and offset can help you out but still it can't be surely said that whether it will fit or not as I haven't tried this till now.
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When choosing a wheel of a truck or jeep, the first to realize how important it is that people need to set up, they are a car. They are based on the actual wheel bolts to the size and offset. Very different wheel size, measured in inches.
I think that Mercedes wheels might be fit on the BMW e36. But Not a Perfectly Fits and It is Effects on a BMW e36 's Average. I suggest You that Please Don't make to this type of Changes in Wheels it may be Harmful.